Benzyl mercaptan — properties & hazards overview

Name: Benzyl mercaptan Formula: C₆H₅CH₂SH CAS: 100-53-8 UN: 3334 (flammable liquid, toxic, corrosive)
DANGER — Toxic, flammable, highly odorous thiol. Causes irritation and nausea at very low concentrations. Use alkaline oxidising scrubbing (e.g., NaOH + NaOCl) with strong ventilation, demisting, and activated carbon polishing.
Boiling point
194 °C
Flash point
≈ 82 °C (closed cup)
Odour threshold
Extremely low (ppb range)
Water solubility
Low (~1 g/L)
Toxicity
inhalation/dermal
Flammability
FP ≈ 82 °C
Chronic risk
CNS / hepatic (suspected)
Environmental
acute aquatic toxicity
PropertyValue / Note
Chemical formulaC₆H₅CH₂SH
Molar mass124.2 g/mol
Physical state (20 °C)Colourless to pale-yellow liquid, intense thiol odour
Density1.06 g/cm³ @ 20 °C
Vapour pressure≈ 0.05 kPa @ 25 °C
Water solubilityLow (~1 g/L); forms emulsions, floats on water
OdourExtremely strong, unpleasant; detectable below 1 ppb
Typical usesOrganic synthesis, polymer modification, fragrance intermediates (trace)

*Values are indicative; always verify with current SDS for design and safety.

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