BTEX — properties & hazards overview

Group: Benzene, Toluene, Ethylbenzene, Xylenes Type: Aromatic VOCs Use: Fuels, solvents, petrochemicals
WARNING — flammable aromatic VOC mixture; benzene is carcinogenic. Water-only scrubbing underperforms → prefer solvent-assisted absorption + activated carbon or catalytic/thermal oxidation. Enforce ATEX & continuous LEL monitoring.
Boiling range
~ 80 – 144 °C
LEL–UEL (air)
≈ 1 – 8 vol%
Water solubility
Low (≈ 150–1,800 mg/L)
Vapour pressure (20 °C)
Moderate → volatile
Toxicity
CNS/irritant (mix)
Flammability
high (LEL ~1%)
Chronic risk
benzene: carcinogenic
Environmental
VOC / aquatic
PropertyValue / Note
Chemical natureAromatic hydrocarbons (mono-substituted benzene ring)
Typical sourcesRefining, fuel storage/dispensing, painting/coatings, printing, solvent use, coking
Water solubility (indicative)Benzene ~1,800 mg/L; Toluene ~520 mg/L; Ethylbenzene ~150 mg/L; Xylenes ~150–200 mg/L
Boiling point (°C)Benzene 80.1; Toluene 110.6; Ethylbenzene 136.2; Xylenes ~138–144
LEL–UEL (vol%)Benzene 1.2–7.8; Toluene 1.2–7.1; Ethylbenzene 1.0–6.7; Xylenes ~1.0–7.0
OdourSweet, solvent-like; odour is not a safe exposure indicator
ReactivityFlammable VOCs; air oxidation possible; photo-oxidation contributes to smog
Notes for scrubbingPoor water solubility → limited removal by simple water scrubbing; consider enhanced absorption or alternative abatement

*Values are indicative and vary by composition and temperature. For design/safety, consult current SDS and local standards.

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