Dibutyl amine (DBA) — properties & hazards overview

Name: Dibutyl amine Formula: C₈H₁₉N CAS: 111-92-2 UN: (check SDS / transport class)
WARNING — Basic, strongly odorous secondary amine; flammable vapours and distinct ammonia/fishy smell at low ppm. Causes eye/skin/airway irritation. Exothermic neutralization with acids (salt formation).
Boiling point
≈ 160 °C
Flash point
≈ 50–60 °C (low–moderate)
Odour threshold
Low (ppm → sub-ppm)
Water solubility
Moderate; high as salt
Flammability
Vapours ignite
Toxicity
Irritant / corrosive (basic)
Chronic risk
Sensitization/odor
Environmental
N-load/COD
PropertyValue / Note
Chemical identity Secondary amine, (C₄H₉)₂NH; clear liquid with strong amine odour.
Molar mass ≈ 129.2 g/mol
Reactivity Strongly basic; rapid salt formation with mineral acids (e.g., sulfate/chloride). Incompatible with strong oxidizers; may attack some plastics/coatings.
Behaviour in gas streams Gas-phase amine with moderate volatility; high capture when protonated in acidic liquor. Mist/aerosol risk if over-acidified or at high gas velocities.
Best analytical detection FTIR (inline) — continuous, selective identification of amine functional groups (N–H, C–N) without reagents; ideal for process/leak monitoring and scrubber outlet control.

*Indicative values; confirm exact limits and handling data via current SDS (“verify via SDS”).

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