Dimethyl Disulfide (DMDS) — properties & hazards overview

Name: Dimethyl disulfide Formula: C₂H₆S₂ CAS: 624-92-0 UN: 2381
WARNING — highly flammable, strong sulfur odourant with very low odour threshold. Vapours are heavier than air and can travel to ignition sources. Use alkaline oxidizing scrubbing, ATEX design, LEL monitoring, and high-efficiency demisting; consider carbon polishing for odour.
Boiling point
~ 110 °C
Flash point (CC)
≈ 15 °C
LEL–UEL (air)
~ 1.1–16 vol%
Water solubility
low (~ 2–3 g/L @ 20–25 °C)
Toxicity
irritant / CNS
Flammability
FP ~15 °C; wide range
Chronic risk
mainly odour/irritation
Environmental
VOC / odour
PropertyValue / Note
Vapour pressure (25 °C)~ 3–4 kPa (moderately volatile)
Vapour density (air=1)~ 3.2 (heavier than air)
Odour / thresholdStrong garlic/sulfur; very low threshold → odour complaints at trace levels
ReactivityOrganic disulfide; oxidizes under strong oxidants to sulfoxides/sulfate
Typical usesCatalyst sulfiding (refining), soil fumigant, chemical intermediate
Notes for scrubbingLow water solubility → use oxidizing alkaline liquor; add activated carbon polishing for odour

*Indicative values; verify with current SDS for design/safety.

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