Dimethyl Sulfide — properties & hazards overview

Name: Dimethyl Sulfide Formula: (CH₃)₂S CAS: 75-18-3 UN: 1163 (flammable liquid)
WARNING — Volatile organic sulfide with very strong odor (rotten cabbage) and low ignition temperature. Toxic at high levels and environmentally persistent. Oxidize to non-odorous sulfate before discharge.
Boiling point
≈ 37 °C
Flash point
−36 °C (CC)
Vapour density
2.1 (air = 1)
Water solubility
Slightly soluble
Flammability
Highly flammable vapor
Toxicity
Irritant / CNS effects
Odour impact
ppb-level detectable
Environmental
Volatile sulfur compound
PropertyValue / Note
Physical state Colorless, volatile liquid with characteristic sulfur odor; vapor heavier than air.
Density (20 °C) ≈ 0.85 g/cm³
Odour threshold ≈ 0.001 ppm — extremely low; odor nuisance at trace levels.
Decomposition products SO₂, H₂S and CO on combustion / oxidation.
Typical sources Pulp & paper, petrochemical streams, biogas desulfurization, thioether manufacture, anaerobic digestion.
Typical analytical detection FTIR: excellent selectivity for S–C stretch; FID: after oxidation to SO₂ or total hydrocarbon measure; NDIR: possible for higher ppm ranges; Sulfur-specific chemiluminescence (SCD) for trace analysis.

*Indicative data; verify via SDS and measurement standard before process design.

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