Diphenyl Sulfide — properties & hazards overview

Name: Diphenyl Sulfide Formula: (C₆H₅)₂S CAS: 139-66-2 UN: not classified / organic sulfide
WARNING — Organic sulfide with strong odor and air oxidation tendency. Vapors irritating; forms SO₂ and H₂S on thermal decomposition. Use oxidizing alkaline scrubber for removal.
Boiling point
≈ 296 °C
Flash point
≈ 143 °C (OC)
Vapour pressure (20 °C)
Very low
Water solubility
Negligible
Flammability
Combustible liquid
Toxicity
Irritant vapors
Odour impact
Strong sulfur odor
Environmental
Persistent sulfidic
PropertyValue / Note
Physical state Oily, colorless to pale-yellow liquid with strong aromatic sulfur odor.
Density (20 °C) ≈ 1.13 g/cm³
Odour threshold Extremely low — detectable at ppb levels (odor nuisance risk).
Decomposition On burning → SO₂ + H₂S + phenyl residues; avoid hot surfaces > 300 °C.
Typical sources Organic sulfidic by-products from thio-ether synthesis, lubricant additives, coal tar distillation, and pyrolysis gas streams.

*Indicative data only — verify via SDS for specific product or mixture.

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