Hydrochloric Acid (solution) — properties & hazards overview

Name: Hydrochloric acid (aqueous) Formula: HCl(aq) CAS: 7647-01-0 UN: 1789 (solution)
WARNING — strongly corrosive acid; fumes at higher concentrations. Inhalation of HCl vapours/aerosols causes severe respiratory irritation. Use alkaline scrubbing with tight pH control and high-efficiency demisting; prevent H₂ generation from metal contact.
HCl content (w/w)
~ 10–37%
pH (20 °C)
< 1 (strong acid)
Density (20 °C)
~ 1.05–1.19 g/cm³ (↑ with %)
Fuming
Yes, at higher % (HCl vapours)
Toxicity
corrosive inhalation
Flammability
not flammable
Chronic risk
respiratory (chronic)
Environmental
acidic/aquatic
PropertyValue / Note
Chemical formulaAqueous solution of hydrogen chloride, HCl in water
Common strengthsTechnical: 30–33%; “concentrated”: up to ~37% w/w
Physical state (20 °C)Clear, colourless to slightly yellow liquid with pungent acid odour
Boiling behaviourHCl–H₂O forms an azeotrope ~20–21% at ~110 °C (approx.)
Vapour / off-gasEmits HCl vapour; off-gassing increases with concentration & temperature (“fuming”)
ReactivityStrong acid; reacts with metals to evolve H₂; highly corrosive to many materials
Typical usesPickling, pH control/neutralisation, metal cleaning, chemical synthesis

*Values are indicative and concentration-dependent. Always consult the latest SDS and local regulations for design and safety.

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