Hydrogen Chloride (anhydrous) — properties & hazards overview

Name: Hydrogen chloride Formula: HCl CAS: 7647-01-0 UN: 1050 (anhydrous gas)
DANGER — corrosive, highly irritating acid gas; forms HCl mist on contact with moisture and pools in low areas. Use alkaline scrubbing with tight pH control, high-efficiency demisting, and segregate from reactive metals to prevent H₂ evolution.
Boiling point
−85 °C
Melting point
−114 °C
Vapour density (air=1)
~ 1.3 (heavier than air)
Water solubility
Very high (forms HCl(aq))
Toxicity
corrosive inhalation
Flammability
not flammable
Chronic risk
respiratory (chronic)
Environmental
acidic/aquatic
PropertyValue / Note
Chemical formulaHCl
Molar mass36.46 g/mol
Physical state (20 °C)Colourless to slightly yellow, pungent gas (liquefies at low temp/high pressure)
Odour / thresholdPungent, irritating / very low ppm range (odour is not a reliable warning)
ReactivityHighly reactive acid gas; forms hydrochloric acid with water (exothermic). Attacks many metals producing H₂.
FlammabilityNon-flammable, but hydrogen evolved from metal corrosion is flammable/explosive.
Typical sources/usesChlorination processes, chemical synthesis, semiconductor/pickling off-gas, PVC production.

*Values are indicative; always verify with a current SDS and applicable standards for design and safety.

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