Hydrogen Fluoride (HF) / Hydrofluoric Acid — properties & hazards overview

Name: Hydrogen fluoride Formula: HF CAS: 7664-39-3 UN: 1052 (anhydrous) / 1790 (solution)
DANGER — severely corrosive & systemically toxic. Fluoride binds Ca²⁺/Mg²⁺ → hypocalcaemia; small skin exposures can be fatal. Use alkaline + calcium scrubbing, HF-resistant materials, and high-efficiency demisting.
Boiling point (HF)
~ 19.5 °C
Water interaction
Very high (forms HF(aq))
Vapour density (air=1)
~ 0.9 (near air)
Flammability
Non-flammable
Toxicity
systemic fluoride
Flammability
not flammable
Chronic risk
fluorosis; delayed injury
Environmental
fluoride discharge
PropertyValue / Note
Physical stateColourless gas/fuming liquid near ambient; strong, irritating odour
SolubilityCompletely miscible with water → hydrofluoric acid (strongly corrosive)
ReactivityAttacks glass, silica, many metals; forms metal fluorides; penetrates tissues
UsesEtching, metal pickling, electronics, fluorochemicals

*Values indicative; HF hazards require specialised procedures and medical readiness.

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