Hydrogen Sulfide — properties & hazards overview

Name: Hydrogen sulfide Formula: H₂S CAS: 7783-06-4 UN: 1053
DANGER — highly toxic & flammable gas; odour becomes unreliable due to olfactory fatigue at high ppm. Heavier than air → accumulation in low areas. Use alkaline oxidising scrubbing, ATEX design, LEL monitoring, and high-efficiency demisting.
Boiling point
−60 °C
Flash point
−82 °C
Explosion limits (air)
4.3–45.5 vol%
Vapour density (air=1)
~ 1.2 (heavier than air)
Toxicity
rapid respiratory paralysis
Flammability
wide explosive range
Chronic risk
mainly acute hazard
Environmental
odour / sulfides
PropertyValue / Note
Chemical formulaH₂S
Molar mass34.08 g/mol
Physical state (20 °C)Colourless gas with characteristic “rotten egg” odour
Odour threshold~ 0.01–0.3 ppm (olfactory fatigue above ~100 ppm — smell is unreliable)
Solubility in waterModerate; forms weak acids (H₂S ⇌ HS⁻ + H⁺)
ReactivityFlammable, corrosive; reacts with metals to form metal sulfides
Typical sources/usesPetroleum refining, natural gas processing, wastewater, pulp & paper, biogas plants

*Values are indicative; always consult current SDS and regulations for design and safety.

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