Sulfur Dioxide — properties & hazards overview

Name: Sulfur dioxide Formula: SO₂ CAS: 7446-09-5 UN: 1079
WARNING — toxic, acidic gas; forms sulfurous/sulfuric acid aerosols with moisture and pools in low areas (heavier than air). Use alkaline scrubbing (NaOH/Na₂CO₃ or lime/limestone), tight pH control, and high-efficiency demisting.
Boiling point
−10.0 °C
Melting point
−72.7 °C
Vapour density (air=1)
~ 2.3 (heavier than air)
Flammability
Non-flammable
Toxicity
strong irritant
Flammability
not flammable
Chronic risk
respiratory effects
Environmental
acid deposition
PropertyValue / Note
Chemical formulaSO₂
Molar mass64.07 g/mol
Physical state (20 °C)Colourless, suffocating gas (liquefies under pressure/low temperature)
Odour / thresholdPungent, choking / ~ 0.3–1 ppm (odour not reliable at higher levels)
Solubility in waterModerate–high; forms sulfurous acid (H₂SO₃/HSO₃⁻)
ReactivityAcidic gas; oxidises to sulfate; corrosive in moist environments
Typical sources/usesCombustion of sulfur fuels, smelters, pulp & paper, food/beverage sterilisation, chemicals

*Values are indicative; verify with current SDS and standards for design and safety.

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