Sulphuric Acid Vapors — properties & hazards overview

Name: Sulphuric Acid (mist/vapor) Formula: H₂SO₄ CAS: 7664-93-9 UN: 1830 (concentrated), 2796 (dilute)
DANGER — Highly corrosive acid mist that causes severe burns and respiratory damage. Non-flammable, but reacts violently with water and organic materials; forms dense white aerosols when released.
Boiling point
≈ 337 °C (decomposes)
Vapour pressure (20 °C)
< 0.001 hPa
Water solubility
Fully miscible
Appearance
Colourless liquid / dense mist
Flammability
Non-flammable
Corrosivity
Severe
Toxicity
Respiratory damage
Environmental
Acidification risk
PropertyValue / Note
Physical state Strong mineral acid; forms white fuming mist in humid air due to water absorption and aerosol generation.
Density (20 °C) ≈ 1.84 g/cm³ (98 %)
Odour Odourless, but extremely irritant in aerosol form.
Typical sources Acid plants, battery charging, pickling lines, fertilizer units, and stack plume condensation.
Best analytical detection Gravimetric / ion-chromatographic analysis of collected mist — air drawn through an isopropanol or water impinger; the captured H₂SO₄ is quantified as sulfate. Direct FTIR/NDIR detection is unsuitable because H₂SO₄ exists mainly as aerosol droplets.

*Values indicative; always verify via current SDS and stack-testing standards (e.g., EPA Method 8, EN 14577).

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